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Physical processes involving charge transfer, spin exchange, or excitation exchange often occur in conditions of resonant scattering. We show that the s-wave contribution can be used to obtain a good approximation for the full cross section. This approximation is found to be valid for a wide range of scattering energies, including high above the Wigner regime, where many partial waves contribute. We derive an analytical expression for the exchange cross section and demonstrate its relationship to the Langevin cross section. We give examples for resonant charge transfer as well as spin-flip and excitation exchange. Our approximation can be used to gain information about the s-wave regime from data obtained at much higher temperatures, which would be advantageous for systems where the ultracold quantum regime is not easily reachable.
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Côté et al. (2018) studied this question.
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