Optically pumped mid-infrared vibrational hydrogen chloride laser

The results of an experimental investigation of an optically pumped vibrational laser in HCl are reported. Two different excitation sources were used: a Nd:yttrium–aluminum–garnet laser pumped optical parametric oscillator and a Raman shifted alexandrite laser. Overtone pumping on the (2,0) and (3,0) bands was employed to produce laser oscillation on the (3,2) and (2,1) bands near 3.8 μm. We also developed a model for the optically pumped laser and compare predictions of the model to the observed behavior of the laser. The photon efficiency of the HCl laser was found to be approximately 60%, consistent with model predictions and with previous optically pumped hydrogen halide lasers.