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Ion-induced assembly: Supramolecular structures are obtained in solution by a new ion-induced assembly of conjugated Schiff-base macrocycles. A distinct color change accompanies the aggregation, as shown in the photo. Shown: Macrocycle (A); with NaBPh4 (B); with KBPh4 (C); with RbBPh4 (D); with CsBPh4 (E); and with NH4BPh4 (F) in CH2Cl2.
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Gallant et al. (2003) studied this question.
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