The second-order kinetics of the oxidation of some aryldimethylamines with lead tetra-acetate in chloroform-acetic anhydride (1 :1 v/v) to give acetamides and formaldehyde follow the equation –d[LTA]/dt=k[LTA][amine]. The obtained ρ value (–2.4 ± 0.5) is consistent with the presence of a positive charge in the transition state.
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Galliani et al. (1976) studied this question.
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