September 6, 2008Journal of the American Chemical Society

A Terminal Borylene Ruthenium Complex: From B−H Activation to Reversible Hydrogen Release

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Authors

GAGilles AlcarazCentre National de la Recherche Scientifique UHUlrike HelmstedtÉcole Nationale Supérieure de Chimie de Montpellier ECEric ClotÉcole Nationale Supérieure de Chimie de Montpellier

Abstract

Starting from RuHCl(H2)(PCy3)2, a terminal ruthenium mesitylborylene complex was obtained via double B-H bond activation of mesitylborane and concomitant release of dihydrogen, such a process being remarkably reversible.

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Alcaraz et al. (2008) studied this question.

synapsesocial.com/papers/6a72a76c5d37378ac1df564b https://doi.org/10.1021/ja805164n

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A Terminal Borylene Ruthenium Complex: From B−H Activation to Reversible Hydrogen Release

Abstract

Discussion

Cite This Study

A Terminal Borylene Ruthenium Complex: From B−H Activation to Reversible Hydrogen Release

Abstract

Discussion

Cite This Study

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