Photocatalytic Dehalogenation of Aromatic Halides on Ta₂O₅-Supported Pt–Pd Bimetallic Alloy Nanoparticles Activated by Visible Light

Dehalogenation of aromatic halides is one important reaction for detoxification and organic synthesis. Photocatalytic dehalogenation with alcohol, a safe hydrogen source, is one promising method; however, systems reported earlier need UV irradiation. We found that Pt–Pd bimetallic alloy nanoparticles (ca. 4 nm) supported on Ta 2 O 5 (PtPd/Ta 2 O 5 ), on absorption of visible light (λ > 450 nm), efficiently promote dehalogenation with 2-PrOH as a hydrogen source. Catalytic dehydrogenation of 2-PrOH on the alloy in the dark produces hydrogen atoms (H) on the particles. Photoexcitation of d electrons on the alloy particles by absorbing visible light produces hot electrons (e hot – ). They efficiently reduce the adsorbed H atoms and produce hydride species (H – ) active for dehalogenation. The catalytic activity depends on the Pt/Pd mole ratio; alloy particles consisting of 70 mol % of Pt and 30 mol % of Pd exhibit the highest activity for dehalogenation.