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March 26, 2018Angewandte Chemie International Edition

Octacarbonyl Anion Complexes of Group Three Transition Metals TM(CO)8− (TM=Sc, Y, La) and the 18‐Electron Rule

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JJJiaye JinTYTao YangXKXin Ke

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Jin et al. (2018) studied this question.

synapsesocial.com/papers/6a72a90eac440176ef2ac957https://doi.org/10.1002/anie.201802590
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Also Consider

Synapse has enriched 4 closely related papers on similar clinical questions. Consider them for comparative context:

  1. 1The Nature of the Transition Metal−Carbonyl Bond and the Question about the Valence Orbitals of Transition Metals. A Bond-Energy Decomposition Analysis of TM(CO)<sub>6</sub><sup>q</sup> (TM<sup>q</sup> = Hf<sup>2</sup><sup>-</sup>, Ta<sup>-</sup>, W, Re<sup>+</sup>, Os<sup>2+</sup>, Ir<sup>3+</sup>)2000 · 253 citations
  2. 2Advanced inorganic chemistry1999 · 14,342 citations
  3. 3The transition metal-carbonyl bond1993 · 126 citations
  4. 4Structure and Bonding of the Isoelectronic Hexacarbonyls [Hf(CO)<sub>6</sub>]<sup>2-</sup>, [Ta(CO)<sub>6</sub>]<sup>-</sup>, W(CO)<sub>6</sub>, [Re(CO)<sub>6</sub>]<sup>+</sup>, [Os(CO)<sub>6</sub>]<sup>2+</sup>, and [Ir(CO)<sub>6</sub>]<sup>3+</sup>:  A Theoretical Study<sup>1</sup>1997 · 132 citations