NEARLY 100 years ago, in 1852, it was stated for the first time, by E. Frankland, that atoms have a definite combining power, which determines the formulas of compounds. Then in 1858 Archibald S. Couper introduced the idea of the valency bond and drew the first structural formulas, and August Kekulk showed that carbon is quadrivalent. This simple valency-bond theory permitted great progress to be made in structural organic chemistry, but structural inorganic chemistry remained largely undeveloped until the present century. With the discovery of the electron and the elucidation of the electronic structure of atoms, it became possible for Gilbert Newton Lewis in 1916 to identify the covalent bond with a pair of electrons shared by two atoms and counting as part of the outer shell of each, and thus to lay the basis for the development of the modern theory of valency, to which Sidgwick, Robinson, and many other chemists have contributed.
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Linus Pauling (1948) studied this question.
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