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October 1, 1992Chemische Berichte

Synthesis and Structure of a New Bis[(trimethylphosphan)titanocene] Complex with a Bridging C₂ Unit

Paul Binger Patrik Müller Petra Philipps Barbara Gabor Richard Mynott Albert T. Herrmann Franz Langhauser Carl Krüger

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Abstract

Bis(trimethylphosphane)titanocene ( 1 ) reacts with 2‐methylene‐1,1‐diphenylcyclopropane ( 2 ) to give red crystalline (η 2 ‐2‐methylene‐1,1‐diphenylcyclopropane)(trimethylphosphane)titanocene ( 3 ). In solution complex 3 degrades smoothly to form the new Cp 2 Ti(PMe 3 ) – C 2 – Ti(PMe 3 )Cp 2 complex 4 , the crystal structure of which has been elucidated by an X‐ray analysis.

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Binger et al. (1992) studied this question.

synapsesocial.com/papers/6a72a912e71d69abee09aac0 https://doi.org/10.1002/cber.19921251007

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