A Simple Dissipation Model for Collisional T‐V Energy Transfer and Association Processes between Atoms and Polyatomic Molecules. II. Numerical Trajectory Results for a Morse Interaction

In this second paper we present exact numerical trajectory results with respect to the collisional system atom/damped harmonic oscillator, as a simple model for collisional interacting gas atom/large polyatomic (or solid‐surface) systems. The dependence of the T‐V energy transfer and possible adsorption processes on the frictional parameter, well depth, mass coefficient and particle velocities are studied, assuming a Morse interaction potential. Consideration of multiple collisional processes in relation to the intramolecular relaxation leads to interesting new results.