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Ta 2 O 5 is the most promising high- k dielectric candidate for metal-insulator-metal (MIM) capacitors, but its dielectric relaxation (DR) currents may cause irrecoverable charge loss, although DR is a universal phenomenon of normal dielectrics. Therefore, the Ta 2 O 5 MIM capacitors DR chasracteristics and their control were investigated. Ta 2 O 5 DR is composed of two components. One component shows t -1 -type time decay, which is assumed to be caused by nonuniformity of electron polarization and is almost of the same order as that of SiN. Thus, its influence on dynamic random access memory (DRAM) operation will be limited. The other component shows t -0.5 -type time decay, which is caused by hydrogen deoxidation of Ta 2 O 5 , and is dominant in the case of deoxidized Ta 2 O 5 DR. It causes about 16% charge loss. Namely, it will have an adverse influence on DRAM operation. N 2 annealing is a possible solution for the reduction of this t -0.5 -type DR.
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Kiyotoshi et al. (2003) studied this question.
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