Stable up to 523 K, the bis(dinitrogen) ruthenium and carbonyldinitrogen ruthenium complexes are formed by reaction of N2 with a carbonyl ruthenium species fixed on dealuminated Y zeolite [Eq. (a)]. A stable trans-dicarbonyldinitrogen ruthenium complex is also formed in the presence of CO at 300 K.
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Mießner et al. (1998) studied this question.
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