Crystal structures of quaternary Li−B−N−H phases were determined using NPD data on the isotopically labeled samples. These phases and the end members LiNH2 and LiBH4 all can be viewed as three-dimensional frameworks consisting of corner- and face-shared {Li[BH4−]n[NH2−]4-n} tetrahedra, n = 0–4, with a general chemical formula Li[BH4]x[NH2]1−x.
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Wu et al. (2008) studied this question.
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