July 2, 2014Angewandte Chemie International Edition

Accessing Zinc Monohydride Cations through Coordinative Interactions

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Authors

PLPaul A. LummisDuquesne University MMMohammad R. MomeniUniversity of Missouri–Kansas City MLMelanie W. Lui

Abstract

We present isolable examples of formal zinc hydride cations supported by N-heterocyclic carbene (NHC) donors, and investigate the dual electrophilic and nucleophilic (hydridic) character of the encapsulated [ZnH](+) units by computational methods and preliminary hydrosilylation catalysis.

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Lummis et al. (2014) studied this question.

synapsesocial.com/papers/6a73d710d080559b4669f346 https://doi.org/10.1002/anie.201404611

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Accessing Zinc Monohydride Cations through Coordinative Interactions

Abstract

Discussion

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Cite This Study

Accessing Zinc Monohydride Cations through Coordinative Interactions

Abstract

Discussion

Member takes

Cite This Study

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