We propose the use of Stark chirped rapid-adiabatic-passage method, a technique in which the energy of a target state is swept through resonance by a slowly varying dynamic Stark shift to induce complete population transfer from the ground $1s$ state to the metastable $2s$ state of the hydrogen atom. Parasitic ionization processes are strongly reduced by using a two-color excitation scheme. Our detailed numerical calculations show that under judicious choice of pulse parameters, up to 98% of the population can be found in the $2s$ state at the end of the process.
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Yatsenko et al. (1999) studied this question.
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