The natural and (+)‐enantiomer of grandisol [ 1 , (1 R ,2 S )‐(+)‐2‐isopropenyl‐1‐methylcyclobutaneethanol] has been synthesized from ( R )‐(—)‐carvone ( 2 ) by employing the intramolecular alkylation of 8 to give 9 as the key step.
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Mori et al. (1992) studied this question.
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