Synthesis and Heavy‐Metal‐Ion Sorption of Pure Sulfophenylenediamine Copolymer Nanoparticles with Intrinsic Conductivity and Stability

Novel copolymer nanoparticles were easily synthesized with a polymerization yield of 59.3 % by an oxidative precipitation polymerization of aniline (AN) and m-sulfophenylenediamine (SP) in HCl without any external stabilizer. The polymerization yield, size, morphology, electroconductivity, solubility, solvatochromism, lead and mercury ion adsorbability of the HCl-doped copolymer salt particles were studied by changing the AN/SP ratio. The AN/SP (80:20) copolymer particles are found to have the minimal number-average diameter(84.4 nm), minimal size polydispersity index (1.149), high stability, good long-term stability, powerful redispersibility in water, high purity, and clean surface because of a complete elimination of the contamination from external stabilizer. The copolymer salts possess a remarkably enhanced solubility, interesting solvatochromism, and widely adjustable electroconductivity moving across nine orders of magnitudes from 10(-9) to 10(0) S cm(-1). The AN/SP (70:30) copolymer particles have the highest Hg2+ adsorbance and adsorptivity of 497.7 mg g(-1) and 98.8 %, respectively, which are much higher values than those of other materials. The sorption mechanism of lead and mercury ions on the particles is proposed. The copolymer bases with 5-10 mol % SP unit show excellent film formability, flexibility, and smooth appearance. The copolymer should be very useful in the fabrication of cost-effective conductive nanocomposite with low percolation threshold and in removal of toxic metallic ions from waste water.