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The labile tellurium cyanide species Te(CN) 2 and Te(CN) 4 have been prepared by treatment of tellurium( IV ) tetrahalides with cyanide. Both are thermosensitive solids and, in addition, the tetracyanide was found to be pyrophoric. The crystal structure of Te(CN) 2 has been determined. The structures of Te(CN) 2 , Te(CN) 4 , and Te(CN) 6 have been calculated at various levels of theory. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)
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Klapötke et al. (2004) studied this question.
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