A modified cyclodextrin stationary phase was used in the resolution of the enantiomers of the cyclodiene insecticides cis- and trans-chlordane, oxychlordane, heptachlor, and other metabolized xenobiotics on a milligram scale by preparative gas chromatography. Enantiomeric excesses of between 42 and >99% were obtained. The enantiomerically pure (or enriched) compounds can be used in studies into the enantioselective degradation of toxic substances present in the environment.
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König et al. (1994) studied this question.
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