Porphyrinic molecular metals rival the organic metals in the range of their properties and surpass them in the tunability of these properties. Such Such tunability is illustrated here by the changes that occur in M(L)X systems upon change of ligand L or metal M or oxidant X. Among the compounds thus produced are Ni(pc)I, the first low-temperature molecular metal that does not contain a chalcogen, and Co(pc) I, the first metal-spine conductor not based on a Pt complex.
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Palmer et al. (1985) studied this question.
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