The new block amphiphilic copolymer, poly(sodium styrenesulfonate- block- vinylnaphthalene) (PSSS- block- VN), was synthesized by nitroxide-mediated “living” radical polymerization in homogeneous solution. The composition of the copolymer was determined by 1 H NMR spectroscopy and elemental analysis. On the basis of GPC, viscometric, and spectroscopic measurements, we proposed that the copolymer adopts a highly compressed, pseudomicellar conformation in aqueous solution.
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Nowakowska et al. (2000) studied this question.
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