Equilibrium and nonequilibrium properties of nonideal many-particle systems are strongly influenced by correlation effects that are well described by generalized quantum kinetic equations, in particular, the Kadanoff-Baym equations (KBE). However, these equations are usually derived under the assumption of the weakening of initial correlations (Bogolyubov's condition) and, therefore, fail to correctly describe the short time behavior. We demonstrate that this assumption is not necessary for the derivation of the KBE. Using functional derivatives techniques, we present a straightforward generalization of the KBE that allows us to include arbitrary initial correlations and that is more general than previous derivations. As a result, an additional collision integral is obtained, which is being damped out after a few collisions. Our results are complemented with numerical investigations showing the effect of initial correlations.
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Semkat et al. (1999) studied this question.
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