On the contrary: Utilizing the [Pd(quinox)]–TBHP catalyst system, protected allylic amines were oxidized with high selectivity for the methyl ketone product. This is contrary to the results obtained by the substrate-controlled Tsuji–Wacker oxidation, which highlights the catalyst-controlled system presented here (see scheme). A variety of N-protecting groups undergo selective oxidation with high ketone selectivity. TBHP=tert-butylhydroperoxide.
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Michel et al. (2010) studied this question.
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