January 1, 1984Journal of the Chemical Society Chemical Communications

A clay-modified electrode with stereoselectivity

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Abstract

An SnO2 glass electrode coated with a Δ-Ru(phen)32+-montmorillonite clay oxidized racemic Co(phen)32+(phen = 1,10-phenanthroline) at 30 °C to produce Λ-Co(phen)32+ with 7% optical purity.

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Cite This Study

Yamagishi et al. (1984) studied this question.

synapsesocial.com/papers/6a75c901469a9f8aa3162486 https://doi.org/10.1039/c39840000452

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Abstract

An SnO2 glass electrode coated with a Δ-Ru(phen)32+-montmorillonite clay oxidized racemic Co(phen)32+(phen = 1,10-phenanthroline) at 30 °C to produce Λ-Co(phen)32+ with 7% optical purity.