All articles of this category The effect of substituents on the feasibility of biomimetic [1,3]-proton shift isomerization of the imines derived from benzyl trifluoromethyl ketone has been studied. Reaction rate was shown to be controlled by the nature of substitution on the N-site of starting imine. Specifically, the electron-withdrawing substituent on the phenyl of N -benzyl group facilitates the azomethine-azomethine isomerization. biomimetic [1,3]-proton shift isomerization
No takes yet. Share an insight, caveat, or question.
Soloshonok et al. (1996) studied this question.