The augmented-plane-wave method, including relativistic corrections, is used to calculate the Knight shift for Pb²⁰⁷ in p-type PbTe. The s character is determined to be 0.59, and the hyperfine parameter to be 1.2 cm^-1. The spin paramagnetic susceptibility, including allowance for g-factor anisotropy, is found to be 5.8×{}10^-8-cgs units at 300^∘{}K, for a hole concentration of 1.5×{}10¹⁸ cm^-3. Under these conditions, the measured Knight shift is 2.34×{}10^-3. The calculated Knight shift is 2.0×{}10^-3.
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Paul Bailey (1968) studied this question.
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