Amine-functionalization of TiO2 nanoparticles, through a solvothermal approach, substantially increases the affinity of CO2 on TiO2 surfaces through chemisorption. This chemisorption allows for more effective activation of CO2 and charge transfer from excited TiO2 , and significantly enhances the photocatalytic rate of CO2 reduction into methane and CO.
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Liao et al. (2014) studied this question.
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