Tunable Thermal Switch via Order–Order Transition in Liquid Crystalline Block Copolymer

Organic material-based thermal switch is drawing much attention as one of the key thermal management devices in organic electronic devices. This study aims at tuning the switching temperature ( T S ) of thermal conductivity by using liquid crystalline block copolymers (BCs) with different order–order transition temperature ( T tr ) related to the types of mesogens in the side chain. The BC films with low T tr of 363 K and high T tr of 395 K exhibit reversible thermal conductivity switching behaviors at T S of ∼360 K and ∼390 K, respectively. The BC films also exhibit thermal conductivity variation originating from the anisotropy of the internal structures: poly(ethylene oxide) domains and liquid crystals. These results demonstrate that the switching behavior is attributed to an order–order transition between BC films with vertically arranged cylinder domains and the ones with ordered sphere domains. This highlights that BCs become a promising thermal conductivity switching material with tailored T S .