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January 1, 1991Journal of the Chemical Society Chemical Communications

A stereoselective total synthesis of (±)-Δ ⁹⁽¹²⁾ -capnellene via the intramolecular Diels–Alder approach

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Abstract

A formal total synthesis of (±)-Δ9(12)-capnellene 1 was achieved by the intramolecular Diels–Alder reaction of the triene 4.

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Cite This Study

Ihara et al. (1991) studied this question.

synapsesocial.com/papers/6a7709bf3da069e66cbd7835 https://doi.org/10.1039/c39910000646

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Synapse has enriched 4 closely related papers on similar clinical questions. Consider them for comparative context:

1Olefin synthesis. Rate enhancement of the elimination of alkyl aryl selenoxides by electron-withdrawing substituentsOriginal Research · 1975 · 295 citations
2Synthesis of (.+-.)-.DELTA.9,12-capnellene using titanium reagentsOriginal Research · 1986 · 163 citations
3Asymmetric total synthesis of (+)-.DELTA.9(12)-capnelleneOriginal Research · 1990 · 45 citations
4The first total syntheses of .DELTA.9(12)-Capnellene-8.beta.,10.alpha.-diol and .DELTA.9(12)-capnellene-3.beta.,8.beta.,10.alpha.-triolOriginal Research · 1986 · 51 citations