Yield of excited CO molecules from dissociative recombination of HCO+ and HOC+ ions with electrons

The authors have investigated CO band emissions arising from the dissociative recombination of HCO(+) and HOC(+) ions with thermal electrons in a flowing afterglow plasma. The quantitative analysis of the band intensities showed that HCO(+) recombination forms the long-lived CO(a (3)Pi) state with a yield of 0.23+/-0.12, while HOC(+) recombination favors formation of CO(a' (3)Sigma(+)) and CO(d (3)Delta) with a combined yield of greater than 0.4. The observed vibrational distribution for the CO(a) state reproduces theoretical predictions quite well. The vibrational distributions for CO(a') and CO(d) are, in part, inverted, presumably as a consequence of a change in CO equilibrium bond length during recombination. The observations are compatible with current knowledge of the potential surfaces of states of HCO and HCO(+).