Complex cubes: In a cationic supramolecular cube, coordinatively unsaturated metal centers in the walls of the host provided binding sites for neutral or negatively charged guests. The binding of an initial guest (CF3CO2−, OPMe3, NH3, or NMe3) either cooperatively enhanced or competitively inhibited the binding of a second guest (halide ion).
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Ramsay et al. (2013) studied this question.
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