Ion‐Conductive Hydrogel‐Based Stretchable, Self‐Healing, and Transparent NO2 Sensor with High Sensitivity and Selectivity at Room Temperature

Abstract Here stretchable, self‐healable, and transparent gas sensors based on salt‐infiltrated hydrogels for high‐performance NO 2 sensing in both anaerobic environment and air at room temperature, are reported. The salt‐infiltrated hydrogel displays high sensitivity to NO 2 (119.9%/ppm), short response and recovery time (29.8 and 41.0 s, respectively), good linearity, low theoretical limit of detection (LOD) of 86 ppt, high selectivity, stability, and conductivity. A new gas sensing mechanism based on redox reactions occurring at the electrode–hydrogel interface is proposed to understand the sensing behaviors. The gas sensing performance of hydrogel is greatly improved by incorporating calcium chloride (CaCl 2 ) in the hydrogel via a facile salt‐infiltration strategy, leading to a higher sensitivity (2.32 times) and much lower LOD (0.06 times). Notably, both the gas sensing ability, conductivity, and mechanical deformability of hydrogels are readily self‐healable after cutting off and reconnection. Such large deformations as 100% strain do not deprive the gas sensing capability, but rather shorten the response and recovery time significantly. The CaCl 2 ‐infiltrated hydrogel shows excellent selectivity of NO 2 , with good immunity to the interference gases. These results indicate that the salt‐infiltrated hydrogel has great potential for wearable electronics equipped with gas sensing capability in both anaerobic and aerobic environments.