This Letter proposes a scheme for obtaining the d-electron energy-band parameters to be used in a simple analytic model of the alloy heat of formation, ΔH. The scheme employs, as an intermediate step, the equalization of the local chemical potentials of the two sites. Calculations for $3d$, $4d$, and $5d$ metal alloys yield ΔH in accord with experimental trends, but, unlike earlier estimates, with d charge transfer in the direction indicated by experiment.
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Watson et al. (1979) studied this question.
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