The thermodynamic behaviour is discussed of a charged black hole in a box in equilibrium with neutral thermal radiation, in the thermodynamic limit (i.e. of a very massive black hole). The heat capacity at constant volume of this system exhibits several types of discontinuities which resemble phase transitions, and in an appropriate phase plane a critical point can be distinguished. The correspondence with normal thermodynamic phase changes is discussed, and various other thought experiments are briefly mentioned.
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P. Hut (1977) studied this question.