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Valence electron calculations have been carried out on the ground states of AgH, Ag2, and AgO and the excited 2∑+ state of AgO using the relativistic effective-core potential (ECP) technique. Nonrelativistic all-electron and valence-electron calculations have also been performed on AgH and AgO. These results are compared to previous theoretical treatments and to existing experimental data. The previously undiscovered 2∑+ state of AgO is predicted to lie 1.29 eV above the 2∏ ground state.
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Hay et al. (1985) studied this question.
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