Effect of Salt Content on the Rheological Properties of Hydrogel Based on Oligomeric Electrolyte

Dynamic light scattering and oscillatory rheology experiments were performed to study the effects of various salts on the hydrogel consisting of an oligomeric electrolyte gelator, poly(pyridinium-1,4-diyliminocarbonyl-1,4-phenylenemethylene chloride) (1-Cl). Sol-gel transition temperature increased with increasing salt concentration that suggested the salt-in behavior. The concentration dependence of the dynamic shear moduli showed power-law scaling behavior and was compared with the predictions made by the fractal gel model. The brittleness was increased by increasing salt concentration, indicating that 1-Cl hydrogel became better packed into stronger networks in ionic solutions. After certain salt concentrations, 1-Cl hydrogel started precipitation that might be due to the excessive network formation resulting in collapse of the network structure. The recovery of the mechanical properties of 1-Cl hydrogel was completely reduced in the presence of salts.