Experimental study demonstrates tunable disulfonylation and sulfinylsulfonylation of alkynes using iodine and light, suggesting flexible sulfur-based functionalization pathways.
The iodine-mediated reaction of alkynes with sodium arylsulfinates under blue light irradiation gives either disulfonylation or sulfinylsulfonation depending on reaction conditions.
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Reddy et al. (2023) studied this question.
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