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Aqueous Zn/MnO 2 batteries (AZMBs) are suitable for large-scale energy storage because of the advantages of safety, low cost and environmentally friendliness. However, the energy storage mechanism in AZMBs is still inconclusive, especially in sulfate-based electrolytes. In this work, we investigate the formation and conversion mechanisms of hydrate zinc sulfate hydroxide, Zn 4 SO 4 ·(OH) 6 ·xH 2 O (ZSH), aiming to elucidate the reaction mechanism and capacity origin of AZMBs with ZnSO 4 and MnSO 4 as the electrolyte. Results show that ZSH is an important intermediate in the electrolyte. It is observed that the electrochemical reaction occurs at the cathode/electrolyte interface involving the generation of ZSH-induced ZnMn 3 O 7 ‧2H 2 O during a long-term cycling. In addition, transformation of ZSH to Zn at the anode/electrolyte interface is observed, implying that ZSH not only induces the uneven deposition of Zn 2+ from electrolyte, but also in-situ converts into metallic Zn during the repeated cycling. This research provides an in-depth understanding of the formation and conversion of ZSH in AZMBs with potential impacts on Zn anode protection.
Huang et al. (Tue,) studied this question.