A novel non-interpenetrated three-dimensional porous metal-organic framework UTSA-68 has been controllably synthesized by altering the reaction conditions. The resulting UTSA-68a shows a notably higher porosity and adsorption selectivity (3.5-5) for C2H2/CO2 separation compared to that of doubly interpenetrated ZJU-30a (1.7-2.4) at room temperature.
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Chang et al. (2016) studied this question.
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