Polypropylene PP (high and low crystallinity) was λ-oxidized, in the presence of air, using different dose rates (from 2 to 100 rad/s). Oxidation outcomes were identified and quantified by FTIR spectroscopy coupled with derivatization reactions (NO and SF4). The difficulty to separate secondary and tertiary hydroperoxides from FTIR measurements after NO treatment was addressed. Polymer physical degradation was also monitored during the λ-irradiation process. GPC was used to follow molecular weight changes and tensile tests for elongation at break modifications. Comparison of the extent of oxidation product for-mation over λ-irradiation allowed us to investigate the importance of λ-dose rate on chemical and physical changes of PP. From this, different mechanisms of ketone and ester formation were examined; relationship between the molecular weight changes and the elongation at break modifications was also investigated.
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Tidjani et al. (1996) studied this question.
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