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The second virial coefficients of the mixtures CH4-A and Ne-Kr have been measured at low temperature. The intermolecular parameters ε* and σ have been deduced assuming a 6–12 Lennard-Jones potential. Comparison is made between these results and those obtained from the pure component parameters using the customary combining laws, i.e. arithmetical mean for σ and geometrical mean for ε*.
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Thomaes et al. (1962) studied this question.
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