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Photon correlation spectroscopy in the polarized light scattering geometry can be employed to study the dynamics of composition fluctuations in disordered diblock copolymer melts near the order‐to‐disorder transition. The origin of a diffusive relaxation mode, very recently measured on a series of undiluted copolymers, can be rationalized in terms of composition polydispersity effects rather than relaxation of equilibrium composition configurations of the fluctuation theory.
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Fytas et al. (1994) studied this question.
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