A tandem radical fragmentation of a cyclopropylcarbinyl/oxiranylcarbinyl system leads to the PGB1 series of prostaglandins. Control of cyclopropane bond fragmentation as a function of C2 substitution in bicyclo[3.1.0]hexanylcarbinyl radicals is presented.
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Ziegler et al. (1996) studied this question.
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