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The structures of the following three disaccharides, isolated from Asclepiadaceae, have been elucidated: Drebyssobiose (1) = 4–0‐(3–0‐methyl‐6‐deoxy‐β‐d‐allopyranosyl)‐d‐digitoxose, lilacinobiose (7) = 4‐O‐(3‐O‐methyl‐6‐deoxy‐β‐d‐glucopyranosyl)‐d‐cymarose, and viminose (13) = 4‐O‐(3‐O‐methyl‐6‐deoxy‐β‐d‐glucopyranosyl)‐d‐digitoxose.
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Hans Allgeier (1968) studied this question.
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