Pt‐Induced Defects Curing on BiVO₄ Photoanodes for Near‐Threshold Charge Separation

Photostability is one of the most essential properties for evaluating photoelectrochemical (PEC) water splitting performance on semiconductors. Herein, the oxygen‐deficiency conditions are applied to tune and activate BiVO 4 photoanodes with a class of oxygen vacancies across the whole bulk material, and regulate the electronic occupancy of these states upon the charge carrier processes that determine PEC water oxidation activity. Through the experimental results and nonadiabatic molecular dynamics with time‐domain density functional theory calculations, the charge carrier lifetime can be influenced by the oxygen vacancies concentration on BiVO 4 , and the semiconductor can be flexibly photoactivated under oxygen‐sufficient and deficient atmospheres for enhancing the charge carrier density and photovoltage. The PEC performance of BiVO 4 is further boosted by Pt doping, which exhibits a record photocurrent density of 5.45 mA cm –2 at 1.23 V RHE with solar conversion efficiency of 2.1% at 0.65 V RHE . The Pt can prevent the unnecessory charge recombination on the defected BiVO 4 , which also enhances the majority charge carrier density, resulting in one of the best charge separation efficiencies, close to 100%, among the steady‐state PEC performance for BiVO 4 . More importantly, the resulting Pt:BiVO 4 presents long‐term stability over 50 h at 0.8 V RHE .