Electrochemical investigation of adsorption of graphene oxide at an interface between two immiscible electrolyte solutions

selected as probe ions. Capacitance measurements show that the interfacial capacitance increases greatly in the presence of GO nanosheets inside the aqueous phase, which can be attributed to the increases of interfacial corrugation and charge density induced by the parallel adsorption and assembly of GO at the L/L interface. In addition, it is found that the application of an interfacial potential difference by external polarization can promote the adsorption of GO at the L/L interface. Moreover, the ion-transfer voltammetric results further demonstrate that the GO layers formed at the interface can suppress the ion transfer reactions due to interfacial blocking and charge screening, as well as the hindrance effect induced by the GO layers. All the results with insights into the interfacial behavior of GO under polarization with an external electric field enable understanding the adsorption behavior of GO at the L/L interface more comprehensively.