Thinking outside the box: placing hydrophilic particles in an oil phase for the formation and stabilization of Pickering emulsions

water phase) conditions such as pH and ionic strength is required. Herein, we present an effective and not yet explored strategy to stabilize Pickering emulsions with unmodified highly hydrophilic particles, strikingly, without changing the solvent conditions. The innovative aspect of the strategy presented here is the unconventional dispersion of hydrophilic particles in an oil phase before emulsification, while the results experimentally demonstrate the theoretical calculations predicted more than a decade ago. This study will promote the diversity of Pickering emulsions and expand their real-world applications.