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August 12, 2026Small

Ultralow‐Iridium‐Stabilized Ruthenium‐Based Alloy/Oxide Catalysts for Durable Acidic Water Oxidation

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Authors

ZWZexuan WuYWYanxiao WanCXChenxuan Xie

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Overview

Randomized trial demonstrates enhanced oxygen evolution efficiency in water electrolysis, implying cost-effective hydrogen production.

Key Points

  • This research aims to address the limitations of costly Ir-based catalysts and stability issues with Ru-based alternatives in water oxidation.
  • Synthesis of Ir and Mn co-doped Ru/RuO₂ heterostructure using a metal-organic framework sacrificial template strategy.
  • Utilization of in situ differential electrochemical mass spectroscopy and infrared spectroscopy to study catalytic performance.
  • Integration of the catalyst into a proton exchange membrane water electrolyzer (PEMWE) device for performance evaluation.
  • The IM-Ru/RuO₂ catalyst shows an overpotential of 182 mV at 10 mA cm⁻² and maintains stability for over 600 hours.
  • The catalyst achieved a hydrogen production cost of US$0.88 kg⁻¹, surpassing U.S. DOE 2031 targets.
  • The OER primarily occurs through an enhanced adsorbate evolution mechanism rather than the detrimental lattice oxygen mechanism.

Cite This Study

Wu et al. (2026) studied this question.

synapsesocial.com/papers/6a7c20ae06a85aed514b79b6https://doi.org/10.1002/smll.75035
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