Mild Rhodium(III)‐Catalyzed Direct CH Allylation of Arenes with Allyl Carbonates

All(yl) possible! A rhodium(III)-catalyzed intermolecular direct CH allylation reaction utilizing readily accessible allyl carbonates was developed. This method allows the allylation of electron-neutral arenes, providing complete γ-selectivity, high isomeric ratio, good substrate scope, and excellent functional group compatibility.