January 1, 1989Journal of the Chemical Society Chemical Communications

Ionic hydrogenations using transition metal hydrides. Rapid hydrogenation of hindered alkenes at low temperature

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Abstract

Tetra-substituted, tri-substituted, and 1,1-disubstituted alkenes can be rapidly hydrogenated in high yield at –75 °C using CF3SO3H/HMo(CO)3(C5H5) or CF3SO3H/HSiEt3.

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Cite This Study

Bullock et al. (1989) studied this question.

synapsesocial.com/papers/6a7c724256517b7105401220 https://doi.org/10.1039/c39890001447

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Abstract

Tetra-substituted, tri-substituted, and 1,1-disubstituted alkenes can be rapidly hydrogenated in high yield at –75 °C using CF3SO3H/HMo(CO)3(C5H5) or CF3SO3H/HSiEt3.